The portrait, taken by photographer Corinne Day in 1990, was shot in London two years after Moss was discovered at a New York airport at age 14.
Another shot taken by Day in 1993 for Vogue magazine, which features a 19-year-old Moss, is expected to sell for £7000.
The Vogue shoot helped propel the grunge movement into the mainstream and launch the infamous "heroin chic" look in the 1990s.
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